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Sodium Halides as Halogenating Reagents: Rhodium(III)‐Catalyzed Versatile and Practical Halogenation of Aryl Compounds
Author(s) -
Zhang Panpan,
Hong Liang,
Li Guofeng,
Wang Rui
Publication year - 2015
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201400590
Subject(s) - halogenation , chemistry , aryl , reagent , halide , nucleophile , halogen , catalysis , rhodium , organic chemistry , combinatorial chemistry , alkyl
We report a concise, versatile and practical method for the ortho ‐chlorination, ortho ‐bromination and ortho ‐iodination of aryl compounds. The significant advantage of this transformation is the creation of the carbon‐halogen bond by use of readily available and cheap halide salts as formal nucleophilic halogenating reagents under mild reaction conditions.