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Dual Photoredox and Gold Catalysis: Intermolecular Multicomponent Oxyarylation of Alkenes
Author(s) -
Hopkinson Matthew N.,
Sahoo Basudev,
Glorius Frank
Publication year - 2014
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201400580
Subject(s) - chemistry , intermolecular force , photoredox catalysis , catalysis , iridium , photocatalysis , photochemistry , combinatorial chemistry , ether , coupling reaction , organic chemistry , molecule
Intermolecular three‐component oxyarylation reactions of simple alkenes have been developed using a dual gold and photoredox catalytic system. Inexpensive organic dyes could be employed as the photocatalyst using aryldiazonium salts, while the combination of gold and iridium catalysts allowed for diaryliodonium compounds to be employed as the source of the arene coupling partner. In both cases, α‐arylated ether products were generated under remarkably mild conditions using readily accessible visible light sources.