Thioesterification of Alkylbenzenes with Thiols  via  Copper‐ Catalyzed Cross‐Dehydrogenative Coupling without a Directing Group | Zendy

Ali Wajid | Zendy; Guin Srimanta | Zendy; Rout Saroj Kumar | Zendy; Gogoi Anupal | Zendy; Patel Bhisma K. | Zendy

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Thioesterification of Alkylbenzenes with Thiols via Copper‐ Catalyzed Cross‐Dehydrogenative Coupling without a Directing Group

Author(s) -

Ali Wajid,

Guin Srimanta,

Rout Saroj Kumar,

Gogoi Anupal,

Patel Bhisma K.

Publication year - 2014

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201400360

Subject(s) - alkylbenzenes , chemistry , thioester , moiety , thiol , copper , functional group , catalysis , group (periodic table) , medicinal chemistry , organic chemistry , combinatorial chemistry , polymer chemistry , stereochemistry , enzyme , polymer

A unique copper‐catalyzed cross‐dehydrogenative coupling (CDC) of thiols and alkylbenzenes has been developed for the synthesis of thioesters without the assistance of any directing group. A thioester moiety is created via successive CS and CO bond formation at the expense of three sp 3 CH bonds of the alkylbenzene and one sp 3 SH bond of the thiol.

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