Photo‐Assisted Multi‐Component Reactions (MCR): A New Entry to 2‐Pyrimidinethiones | Zendy

Guo Haiheng | Zendy; Zhu Chenghao | Zendy; Li Jian | Zendy; Xu Guangyang | Zendy; Sun Jiangtao | Zendy

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Photo‐Assisted Multi‐Component Reactions (MCR): A New Entry to 2‐Pyrimidinethiones

Author(s) -

Guo Haiheng,

Zhu Chenghao,

Li Jian,

Xu Guangyang,

Sun Jiangtao

Publication year - 2014

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201400290

Subject(s) - chemistry , component (thermodynamics) , condensation , combinatorial chemistry , condensation reaction , reaction conditions , multi component reaction , organic chemistry , catalysis , thermodynamics , physics

A photo‐assisted metal‐free multi‐component dehydrogenative condensation has been developed. This multi‐component reaction (MCR) has been realized under mild reaction conditions especially under household light irradiation. As a result, the novel tetrahydropyrimidines (THPMs) were obtained in moderate yields and excellent stereoselectivities. Moreover, the approach provided an easy construction of a variety of 2‐pyrimidinethiones from the commonly used cyclic ethers.

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