Palladium‐Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H‐Phosphonates | Zendy

Candy Mathieu | Zendy; Rousseaux Sophie A. L. | Zendy; San Román Alberto Cirugeda | Zendy; Szymczyk Monika | Zendy; Kafarski Pawel | Zendy; Leclerc Eric | Zendy; Vrancken Emmanuel | Zendy; Campagne JeanMarc | Zendy

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Palladium‐Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H‐Phosphonates

Author(s) -

Candy Mathieu,

Rousseaux Sophie A. L.,

San Román Alberto Cirugeda,

Szymczyk Monika,

Kafarski Pawel,

Leclerc Eric,

Vrancken Emmanuel,

Campagne JeanMarc

Publication year - 2014

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201400190

Subject(s) - palladium , regioselectivity , catalysis , chemistry , organic chemistry , medicinal chemistry

The palladium‐catalyzed hydrophosphonylation of alkenes with previously unreactive acyclic dialkyl H‐phosphonates has been developed. A catalyst system based on palladium/DavePhos or palladium/SPhos enables the transformation of various alkenes to phosphonates in moderate to good yields and with excellent levels of regioselectivity. Hydrophosphonylations with internal, disubstituted and/or unactivated alkenes are also reported.

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