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Site Selective Synthesis of Pentaarylpyridines via Multiple Suzuki–Miyaura Cross‐Coupling Reactions
Author(s) -
Reimann Sebastian,
Ehlers Peter,
Petrosyan Andranik,
Kohse Stefanie,
Spannenberg Anke,
Surkus Annette E.,
Ghochikyan Tariel V.,
Saghyan Ashot S.,
Lochbrunner Stefan,
Kühn Oliver,
Ludwig Ralf,
Langer Peter
Publication year - 2014
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201400164
Subject(s) - chemistry , coupling reaction , suzuki reaction , coupling (piping) , spectroscopy , combinatorial chemistry , catalysis , palladium , organic chemistry , mechanical engineering , physics , quantum mechanics , engineering
Pentaarylpyridines were conveniently prepared in one step by pentafold Suzuki–Miyaura reactions of pentachloropyridine. Moreover, site selective reactions were performed, leading to various substituted arylpyridines. Pentaarylpyridines were studied in detail by means of DFT calculations and by optical spectroscopy.