Premium
Copper(I)‐Induced Sulfenylation of H‐Phosphonates, H‐Phosphonites and Phosphine Oxides with Aryl/alkylsulfonylhydrazides as a Thiol Surrogate
Author(s) -
Kumaraswamy Gullapalli,
Raju Ragam
Publication year - 2014
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201400116
Subject(s) - chemistry , phosphine , aryl , thiophosphate , thiol , copper , iodide , combinatorial chemistry , stoichiometry , organic chemistry , catalysis , alkyl
Aerobic dehydrogenative sulfenylation of H‐phosphonites, and phosphine oxides with aryl/alkylsulfonyl hydrazides catalyzed by a sub‐stoichiometric amount of copper iodide has been accomplished. This protocol is compatible with functional groups, and results in various thiophosphate derivatives in good to high yields.