Visible Light Photoredox Catalysis: Investigation of Distal  sp  3  CH Functionalization of Tertiary Amines for Alkylation Reaction | Zendy

Pandey Ganesh | Zendy; Jadhav Deepak | Zendy; Tiwari Sandip Kumar | Zendy; Singh Bhawana | Zendy

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Visible Light Photoredox Catalysis: Investigation of Distal sp 3 CH Functionalization of Tertiary Amines for Alkylation Reaction

Author(s) -

Pandey Ganesh,

Jadhav Deepak,

Tiwari Sandip Kumar,

Singh Bhawana

Publication year - 2014

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201400107

Subject(s) - alkylation , chemistry , photoredox catalysis , alkyl , catalysis , surface modification , visible spectrum , photochemistry , medicinal chemistry , organic chemistry , photocatalysis , physics , optoelectronics

Visible light‐mediated photoredox activation of 10‐methyl‐9,10‐dihydroacridine in the presence of electron‐deficient alkenes leads to selective γ‐ sp 3 CH alkylation whereby 4‐alkyl‐ N,N‐ dimethylanilines produce substituted tetrahydroquinolines by a subsequent alkylation/cyclization sequence involving interesting mechanistic pathways.

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