Catalytic Enantioselective Synthesis of α‐Arylaminocyclobutanones | Zendy

Aitken David J. | Zendy; Caboni Pierluigi | Zendy; Eijsberg Hendrik | Zendy; Frongia Angelo | Zendy; Guillot Régis | Zendy; Ollivier Jean | Zendy; Piras Pier Paolo | Zendy; Secci Francesco | Zendy

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Catalytic Enantioselective Synthesis of α‐Arylaminocyclobutanones

Author(s) -

Aitken David J.,

Caboni Pierluigi,

Eijsberg Hendrik,

Frongia Angelo,

Guillot Régis,

Ollivier Jean,

Piras Pier Paolo,

Secci Francesco

Publication year - 2014

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201301021

Subject(s) - enantioselective synthesis , chemistry , amadori rearrangement , enol , tautomer , catalysis , condensation , tandem , organic chemistry , stereochemistry , combinatorial chemistry , biochemistry , glycation , composite material , thermodynamics , physics , receptor , materials science

A catalytic enantioselective synthesis of α‐arylaminocyclobutanones from racemic α‐hydroxycyclobutanone and a selection of N ‐alkylanilines has been established, via a tandem condensation/keto‐enol tautomerization process reminiscent of the Amadori and Heyns rearrangements.

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