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Rhodium(III)‐Catalyzed Oxidative Olefination of Picolinamides: Convenient Synthesis of 3‐Alkenylpicolinamides
Author(s) -
Zhou Jun,
Li Bo,
Qian ZhenChao,
Shi BingFeng
Publication year - 2014
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201300895
Subject(s) - chemistry , rhodium , regioselectivity , catalysis , yield (engineering) , functional group , oxidative phosphorylation , combinatorial chemistry , organic chemistry , biochemistry , materials science , polymer , metallurgy
A rhodium(III)‐catalyzed selective olefination of picolinamide derivatives has been developed. The reaction shows high regioselectivity, low catalyst loading (0.5 mol%), high yield and good functional group tolerance, providing a convenient strategy for the synthesis of 3‐alkenylpicolinamides.