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Iron Chloride‐Catalyzed Three‐Component Domino Sequences: Syntheses of Functionalized α‐Oxy‐ N ‐acylhemiaminals and α‐Oxyimides
Author(s) -
Drouet Fleur,
Zhu Jieping,
Masson Géraldine
Publication year - 2013
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201300847
Subject(s) - chemistry , domino , catalysis , iron(iii) chloride , chloride , component (thermodynamics) , combinatorial chemistry , organic chemistry , physics , thermodynamics
The iron(III) chloride‐multicatalyzed dioxygenation of enamides with TEMPO in the presence of alcohols has been developed. This multicomponent domino process affords efficient new strategies for the synthesis of α‐oxy‐ N ‐acylhemiaminals or α‐oxyimides in good to excellent yields under mild conditions.