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Palladium‐Catalyzed Direct Oxidative CH Cross‐Coupling of Azoarenes with Alcohols
Author(s) -
Tang Hui,
Qian Cheng,
Lin Dongen,
Jiang Huanfeng,
Zeng Wei
Publication year - 2014
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201300812
Subject(s) - chemistry , palladium , catalysis , oxidative phosphorylation , cascade , oxidative coupling of methane , coupling (piping) , coupling reaction , organic chemistry , combinatorial chemistry , chromatography , mechanical engineering , biochemistry , engineering
A palladium‐catalyzed cascade oxidative CH cross‐coupling of azoarenes with alcohols was developed using tert ‐butyl hydroperoxide (TBHP) as oxidant. This reaction provides a convenient access to ortho ‐acylazoarenes under mild conditions in which readily available alcohols were used as the acyl sources.