Palladium‐Catalyzed Intermolecular C‐2 Alkenylation of Indoles Using Oxygen as the Oxidant | Zendy

Yan ZhaoLei | Zendy; Chen WenLiang | Zendy; Gao YaRu | Zendy; Mao Shuai | Zendy; Zhang YanLei | Zendy; Wang YongQiang | Zendy

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Palladium‐Catalyzed Intermolecular C‐2 Alkenylation of Indoles Using Oxygen as the Oxidant

Author(s) -

Yan ZhaoLei,

Chen WenLiang,

Gao YaRu,

Mao Shuai,

Zhang YanLei,

Wang YongQiang

Publication year - 2014

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201300811

Subject(s) - chemistry , palladium , stereoselectivity , intermolecular force , catalysis , oxygen , regioselectivity , oxygen atom , medicinal chemistry , organic chemistry , photochemistry , stereochemistry , molecule

A general and efficient palladium‐catalyzed intermolecular direct C‐2 alkenylation of indoles using oxygen as the oxidant has been developed. The reaction is of complete regio‐ and stereoselectivity. All products are E ‐isomers at the C‐2‐position with no Z ‐isomers and 3‐substituted products were detected.

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