Palladium‐Catalysed Dehydrogenative  sp  3  CH Bonds Functionalisation into Alkenes: A Direct Access to  N ‐Alkenylbenzenesulfonamides | Zendy

Bheeter Charles B. | Zendy; Jin Rongwei | Zendy; Bera Jitendra K. | Zendy; Dixneuf Pierre H. | Zendy; Doucet Henri | Zendy

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Palladium‐Catalysed Dehydrogenative sp 3 CH Bonds Functionalisation into Alkenes: A Direct Access to N ‐Alkenylbenzenesulfonamides

Author(s) -

Bheeter Charles B.,

Jin Rongwei,

Bera Jitendra K.,

Dixneuf Pierre H.,

Doucet Henri

Publication year - 2014

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201300795

Subject(s) - palladium , dehydrogenation , moiety , chemistry , catalysis , medicinal chemistry , hydrogen bond , photochemistry , polymer chemistry , stereochemistry , organic chemistry , molecule

The palladium‐catalysed dehydrogenation of sp 3 carbon‐hydrogen bonds of N ‐alkylbenzenesulfonamides allows a simple access to N ‐alkenylbenzenesulfonamides. The reaction proceeds with easily accessible catalysts, with pivalate as a base, and allows a variety of substituents both on nitrogen and on the arene moiety.

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