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Palladium‐Catalysed Dehydrogenative sp 3 CH Bonds Functionalisation into Alkenes: A Direct Access to N ‐Alkenylbenzenesulfonamides
Author(s) -
Bheeter Charles B.,
Jin Rongwei,
Bera Jitendra K.,
Dixneuf Pierre H.,
Doucet Henri
Publication year - 2014
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201300795
Subject(s) - palladium , dehydrogenation , moiety , chemistry , catalysis , medicinal chemistry , hydrogen bond , photochemistry , polymer chemistry , stereochemistry , organic chemistry , molecule
The palladium‐catalysed dehydrogenation of sp 3 carbon‐hydrogen bonds of N ‐alkylbenzenesulfonamides allows a simple access to N ‐alkenylbenzenesulfonamides. The reaction proceeds with easily accessible catalysts, with pivalate as a base, and allows a variety of substituents both on nitrogen and on the arene moiety.