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Chemoselective Carbon‐Carbon Cross‐Coupling via Palladium‐Catalyzed Copper‐Mediated CS Cleavage of Disulfides
Author(s) -
Quan ZhengJun,
Lv Ying,
Jing FuQiang,
Jia XiaoDong,
Huo CongDe,
Wang XiCun
Publication year - 2014
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201300776
Subject(s) - chemistry , palladium , cleavage (geology) , copper , catalysis , reinforced carbon–carbon , bond cleavage , carbon fibers , coupling reaction , coupling (piping) , combinatorial chemistry , polymer chemistry , organic chemistry , composite number , engineering , mechanical engineering , materials science , geotechnical engineering , fracture (geology) , composite material
An efficient method for carbon‐carbon bond formation is described. The process employs the palladium‐catalyzed copper‐mediated cross‐coupling of diheteroaryl disulfides with arylboronic acids or alkynes to deliver CC coupling products through unreactive CS bond cleavage. The scope of the coupling reactions, including both the disulfides and arylboronic acids or alkynes, are documented.