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Adhesive Catalyst Immobilization of Palladium Nanoparticles on Cotton and Filter Paper: Applications to Reusable Catalysts for Sequential Catalytic Reactions
Author(s) -
Nishikata Takashi,
Tsutsumi Hironori,
Gao Lei,
Kojima Keisuke,
Chikama Katsumi,
Nagashima Hideo
Publication year - 2014
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201300691
Subject(s) - catalysis , chemistry , palladium , halide , adhesive , nanoparticle , filter (signal processing) , filter paper , polymer , coupling reaction , polymer chemistry , chemical engineering , combinatorial chemistry , organic chemistry , chromatography , engineering , computer science , computer vision , layer (electronics)
Palladium nanoparticles dispersed in ammonium salts of hyperbranched polystyrenes are adhesively immobilized on the surface of cotton or filter papers by simply heating with dicarboxylic acids or halide anions. The resulting Pd@cotton and Pd@filter paper behave as reusable catalysts; in particular, Pd@filter paper is useful as catalyst for application to sequential cross‐coupling and hydrogenation reactions to produce several different products with just one piece of the paper catalyst.