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Palladium‐Catalyzed Carbonylative Synthesis of Phthalimides from 1,2‐Dibromoarenes with Molybdenum Hexacarbonyl as Carbon Monoxide Source
Author(s) -
Wu XiaoFeng,
Oschatz Stefan,
Sharif Muhammad,
Flader Anika,
Krey Lisa,
Beller Matthias,
Langer Peter
Publication year - 2013
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201300585
Subject(s) - phthalimides , chemistry , carbon monoxide , catalysis , palladium , molybdenum , benzene , carbonylation , monoxide , organic chemistry , inorganic chemistry , phthalimide
We describe here a convenient and mild, carbon monoxide gas‐free palladium‐catalyzed procedure to obtain N ‐substituted phthalimides with molybdenum hexacarbonyl as carbon monoxide precursor. These conditions tolerate a number of functional groups on the benzene ring as well as a number of amines and give the corresponding phthalimides in good to excellent yields.