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Gold(I)‐Catalyzed Bis‐Alkynylation Reaction of Aromatic Aldehydes with Alkynylsilanes
Author(s) -
Rubial Belén,
Ballesteros Alfredo,
González José M.
Publication year - 2013
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201300578
Subject(s) - alkynylation , chemistry , catalysis , organic chemistry , combinatorial chemistry
The first successful gold(I)‐catalyzed reaction of aryl aldehydes with trimethyl(arylethynyl)silanes to furnish bis‐alkynylated derivatives is reported. Key CC bond‐forming events involved in the catalytic cycle are analyzed.