Hydrido‐Cobalt Catalyst as a Selective Tool for the Dimerisation of Arylacetylenes: Scope and Theoretical Studies | Zendy

Ventre Sandrine | Zendy; Derat Etienne | Zendy; Amatore Muriel | Zendy; Aubert Corinne | Zendy; Petit Marc | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Hydrido‐Cobalt Catalyst as a Selective Tool for the Dimerisation of Arylacetylenes: Scope and Theoretical Studies

Author(s) -

Ventre Sandrine,

Derat Etienne,

Amatore Muriel,

Aubert Corinne,

Petit Marc

Publication year - 2013

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201300486

Subject(s) - chemistry , cobalt , catalysis , stereoselectivity , scope (computer science) , combinatorial chemistry , computational chemistry , medicinal chemistry , stereochemistry , photochemistry , organic chemistry , computer science , programming language

A simple hydrido‐cobalt complex efficiently catalyses the highly regio‐ and stereoselective dimerisation of various terminal arylacetylenes under mild conditions. The corresponding ( E )‐1,4‐enynes are obtained as sole isomers with good to excellent yields. DFT calculations revealed that the reaction proceeds via a CH activation/hydrocobaltation pathway.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research