Combining Visible Light Catalysis and Transition Metal Catalysis for the Alkylation of Secondary Amines | Zendy

Gao XueWang | Zendy; Meng QingYuan | Zendy; Xiang Ming | Zendy; Chen Bin | Zendy; Feng Ke | Zendy; Tung ChenHo | Zendy; Wu LiZhu | Zendy

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Combining Visible Light Catalysis and Transition Metal Catalysis for the Alkylation of Secondary Amines

Author(s) -

Gao XueWang,

Meng QingYuan,

Xiang Ming,

Chen Bin,

Feng Ke,

Tung ChenHo,

Wu LiZhu

Publication year - 2013

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201300311

Subject(s) - chemistry , catalysis , visible spectrum , alkylation , transition metal , photochemistry , oxidative coupling of methane , metal , photoredox catalysis , photocatalysis , organic chemistry , physics , optoelectronics

By combining the visible‐light catalyst, Ru(bpy) 3 Cl 2 , and transition metal salts, Cu(OTf) 2 , we are able to functionalize secondary amines to form C sp 3 C sp 3 bonds with β‐keto esters efficiently by an aerobic oxidative coupling reaction under visible light irradiation at ambient conditions.

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