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Tandem Gold‐Catalyzed Hydrosilyloxylation–Aldol and –Mannich Reaction with Alkynylaryloxysilanols in 6‐ exo Mode
Author(s) -
Lee Euichul,
Ryu Taekyu,
Park Youngchul,
Park Sangjune,
Lee Phil Ho
Publication year - 2013
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201300244
Subject(s) - chemistry , aldol reaction , tandem , catalysis , mannich reaction , silylation , silyl enol ether , silyl ether , enol , cascade reaction , organic chemistry , combinatorial chemistry , materials science , composite material
The tandem gold‐catalyzed hydrosilyloxylation–aldol and hydrosilyloxylation–Mannich reactions were developed through the formation of an enol silyl ether catalytically generated in situ from alkynylaryloxysilanols in the 6‐ exo mode in one reaction vessel.