Metal‐Free Direct CH Perfluoroalkylation of Arenes and Heteroarenes Using a Photoredox Organocatalyst | Zendy

Cui Lei | Zendy; Matusaki Yoko | Zendy; Tada Norihiro | Zendy; Miura Tsuyoshi | Zendy; Uno Bunji | Zendy; Itoh Akichika | Zendy

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Metal‐Free Direct CH Perfluoroalkylation of Arenes and Heteroarenes Using a Photoredox Organocatalyst

Author(s) -

Cui Lei,

Matusaki Yoko,

Tada Norihiro,

Miura Tsuyoshi,

Uno Bunji,

Itoh Akichika

Publication year - 2013

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201300199

Subject(s) - chemistry , trifluoromethylation , photoredox catalysis , anthraquinone , combinatorial chemistry , catalysis , organic chemistry , photochemistry , photocatalysis , trifluoromethyl , alkyl

We report the visible‐light‐induced trifluoromethylation of arenes and heteroarenes using sodium trifluoromethanesulfinate catalyzed by anthraquinone‐2‐carboxylic acid. This reaction is a metal‐free trifluoromethylation of arenes and heteroarenes catalyzed by a photoredox organocatalyst. Perfluoroalkylated arenes were also produced using sodium perfluoroalkylsulfinates.

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