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Metal‐Free Direct CH Perfluoroalkylation of Arenes and Heteroarenes Using a Photoredox Organocatalyst
Author(s) -
Cui Lei,
Matusaki Yoko,
Tada Norihiro,
Miura Tsuyoshi,
Uno Bunji,
Itoh Akichika
Publication year - 2013
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201300199
Subject(s) - chemistry , trifluoromethylation , photoredox catalysis , anthraquinone , combinatorial chemistry , catalysis , organic chemistry , photochemistry , photocatalysis , trifluoromethyl , alkyl
We report the visible‐light‐induced trifluoromethylation of arenes and heteroarenes using sodium trifluoromethanesulfinate catalyzed by anthraquinone‐2‐carboxylic acid. This reaction is a metal‐free trifluoromethylation of arenes and heteroarenes catalyzed by a photoredox organocatalyst. Perfluoroalkylated arenes were also produced using sodium perfluoroalkylsulfinates.