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Rhodium‐Catalyzed CH Olefination of Aryl Weinreb Amides
Author(s) -
Wang Yan,
Li Chao,
Li Yan,
Yin Feng,
Wang XiSheng
Publication year - 2013
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201300174
Subject(s) - rhodium , chemistry , aryl , catalysis , reactivity (psychology) , combinatorial chemistry , functional group , organic chemistry , oxidative phosphorylation , biochemistry , polymer , pathology , medicine , alkyl , alternative medicine
A rhodium(III)‐catalyzed oxidative CH olefination directed by Weinreb amides, a class of well developed versatile building blocks in organic synthesis, has been developed with air as the terminal oxidant. The reactions proceed with excellent reactivity, good functional group tolerance and high yields.