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Iron‐Catalysed Borylation of Arenediazonium Salts to Give Access to Arylboron Derivatives via Aryl(amino)boranes at Room Temperature
Author(s) -
Marciasini Ludovic D.,
Richy Nicolas,
Vaultier Michel,
Pucheault Mathieu
Publication year - 2013
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201200942
Subject(s) - borylation , boranes , chemistry , aryl , boron , ferrocene , organic chemistry , combinatorial chemistry , medicinal chemistry , alkyl , electrode , electrochemistry
Complementary to previously described Miyaura borylation methods, a new access to boron derivatives via aryl(amino)boranes is described. Direct coupling between aryldiazonium salts and diisopropylaminoborane is catalysed by 0.1% ferrocene leading to the formation of a carbon‐boron bond. The obtained aryl(amino)boranes could eventually then be transformed into boronic acids, boronates or borates.