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Phosphine‐Free Palladium‐Catalyzed Decarboxylative Coupling of Alkynylcarboxylic Acids with Aryl and Heteroaryl Halides
Author(s) -
Reddy Police Vishnuvardhan,
Srinivas Pottabathula,
Annapurna Manne,
Bhargava Suresh,
Wagler Jorg,
Mirzadeh Nedaossadat,
Kantam Mannepalli Lakshmi
Publication year - 2013
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201200876
Subject(s) - chemistry , halide , palladium , aryl , phosphine , catalysis , decarboxylation , organic chemistry , coupling (piping) , combinatorial chemistry , medicinal chemistry , alkyl , mechanical engineering , engineering
We herein report the design and development of a carboxyamido/carbene ligand and its Pd‐complex for the decarboxylative coupling of alkynylcarboxylic acids with aryl and heteroaryl halides to afford arylalkynes.