Iron‐Catalyzed Tandem One‐Pot Addition and Cyclization of the Blaise Reaction Intermediate and Nitroolefins: Synthesis of Substituted NH‐Pyrroles from Nitriles | Zendy

Zhao MiNa | Zendy; Liang Hao | Zendy; Ren ZhiHui | Zendy; Guan ZhengHui | Zendy

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Iron‐Catalyzed Tandem One‐Pot Addition and Cyclization of the Blaise Reaction Intermediate and Nitroolefins: Synthesis of Substituted NH‐Pyrroles from Nitriles

Author(s) -

Zhao MiNa,

Liang Hao,

Ren ZhiHui,

Guan ZhengHui

Publication year - 2013

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201200673

Subject(s) - chemistry , tandem , catalysis , functional group , reaction conditions , cascade reaction , michael reaction , combinatorial chemistry , medicinal chemistry , organic chemistry , addition reaction , broad spectrum , materials science , composite material , polymer

The iron‐catalyzed addition and cyclization of the Blaise reaction intermediate and nitroolefins to synthesize highly functionalized NH‐pyrroles in a tandem one‐pot manner from nitriles has been developed. This reaction shows good functional group tolerance and affords a broad spectrum of substituted NH‐pyrroles in good yields.

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