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The Reaction of Tertiary Anilines with Maleimides under Visible Light Redox Catalysis
Author(s) -
Ju Xuhui,
Li Dianjun,
Li Weifei,
Yu Wei,
Bian Fengling
Publication year - 2012
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201200608
Subject(s) - chemistry , ruthenium , photocatalysis , catalysis , visible spectrum , redox , iridium , photochemistry , aryl , photoredox catalysis , organic chemistry , physics , alkyl , optoelectronics
Tertiary anilines can be prompted to react with N ‐aryl‐ and N ‐benzylmaleimides to form tetrahydroquinoline products under photocatalysis using visible light irradiation, the ruthenium or iridium complexes Ru(bpy) 3 Cl 2 or Ir(ppy) 2 (dtbbpy)PF 6 as catalyst, and air as terminal oxidant.