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Photochemically Induced Silylacylations of Alkynes with Acylsilanes
Author(s) -
Zhang HuiJun,
Becker Peter,
Huang He,
Pirwerdjan Ramona,
Pan FangFang,
Bolm Carsten
Publication year - 2012
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201200510
Subject(s) - chemistry , stereoselectivity , chromone , photochemistry , atom (system on chip) , transformation (genetics) , alkyne , catalysis , stereochemistry , organic chemistry , biochemistry , computer science , gene , embedded system
Visible light initiates the stereoselective formation of two new bonds, a CC and a CSi bond, during the addition of acylsilanes to alkynes. At room temperature this photochemically induced transformation can be applied for the preparation of chromone derivatives in a highly atom‐economic manner.
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