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Catalytic CSe Bond Formation under Very Mild Conditions for the Two‐Step, One‐Pot Synthesis of Aryl Selenoacetates
Author(s) -
Grenader Konstantin,
Schüpbach Björn,
Peters Annabell,
Kümmel Oliver,
Halter Oliver,
Terfort Andreas
Publication year - 2012
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201200486
Subject(s) - chemistry , aryl , halide , catalysis , palladium , biphenyl , combinatorial chemistry , molecule , reaction conditions , organic chemistry , alkyl
Using the palladium/2‐(dicyclohexylphosphino)‐2′,6′‐di(isopropoxy)biphenyl (RuPhos) catalyst, aryl halides and tricyclohexylsilyl selenol can be efficiently coupled to the respective aryl tricyclohexylsilyl selenides. These can be transformed in the same reaction vessel to the corresponding selenoacetates, permitting a straightforward access to a range of molecules potentially useful for materials science applications.