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Metal‐Free, Visible Light‐Induced Borylation of Aryldiazonium Salts: A Simple and Green Synthetic Route to Arylboronates
Author(s) -
Yu Jian,
Zhang Ling,
Yan Guobing
Publication year - 2012
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201200416
Subject(s) - borylation , chemistry , eosin y , visible spectrum , catalysis , combinatorial chemistry , photochemistry , green chemistry , nanotechnology , organic chemistry , photocatalysis , reaction mechanism , aryl , alkyl , physics , materials science , optoelectronics
The eosin Y‐catalyzed borylation of aryldiazonium salts under irradiation with visible light has been developed. This novel protocol provides an attractive route for the preparation of arylboronates, due to its operational simplicity and practicability as well as the mild reaction conditions.