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A New Method for Intramolecular Chloroamination of Unfunctionalized Olefins
Author(s) -
Liu GongQing,
Li Wei,
Li YueMing
Publication year - 2013
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201200352
Subject(s) - chemistry , intramolecular force , chlorine , chloride , polymer chemistry , copper , organic chemistry
A new method for the intramolecular chloroamination of unfunctionalized olefins is reported. The reactions were carried out at room temperature for 3 h using hydrated copper(II) chloride as both promoter and chlorine source, and the corresponding vincinal haloamines were obtained in good isolated yields.