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Dehydrogenative Silylation of Terminal Alkynes with Hydrosilanes under Zinc–Pyridine Catalysis
Author(s) -
Tsuchimoto Teruhisa,
Fujii Masakazu,
Iketani Yoshihiko,
Sekine Masaru
Publication year - 2012
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201200310
Subject(s) - chemistry , silylation , pyridine , trifluoromethanesulfonate , nitrile , catalysis , zinc , terminal (telecommunication) , organic chemistry , combinatorial chemistry , medicinal chemistry , telecommunications , computer science
A combination of zinc triflate and pyridine in a nitrile medium was found to act as an effective catalytic system for dehydrogenative silylation with flexible pieces of terminal alkynes and hydrosilanes, thereby producing diverse alkynylsilanes in high to excellent yields.