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Synthesis of Aryl Carbamates via Copper‐Catalyzed Coupling of Aryl Halides with Potassium Cyanate
Author(s) -
Yang Xinye,
Zhang Yihua,
Ma Dawei
Publication year - 2012
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201200296
Subject(s) - chemistry , aryl , halide , cyanate , catalysis , iodide , copper , potassium , organic chemistry , medicinal chemistry , combinatorial chemistry , polymer chemistry , alkyl
Coupling of aryl halides with potassium cyanate takes place at 100–110 °C in alcohols under the catalysis of CuI (cuprous iodide) and 2‐(2,6‐dimethylphenylamino)‐2‐oxoacetic acid, affording the corresponding aryl carbamates with great diversity.