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The Role of Metal Hydroxide Complexes in Late Transition Metal‐Mediated Transmetalation Reaction: The Case of Gold
Author(s) -
Dupuy Stéphanie,
Crawford L. Ellis,
Bühl Michael,
Slawin Alexandra M. Z.,
Nolan Steven P.
Publication year - 2012
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201200233
Subject(s) - transmetalation , chemistry , aryl , facilitator , transition metal , hydroxide , metal , stille reaction , organic chemistry , catalysis , alkyl , political science , law
Abstract In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold‐aryl bonds.