The Halonium Ion‐Mediated CC Bond Cleavage of Cyclohexene‐Fused Isoxazoline  N ‐Oxides | Zendy

Raihan Mustafa J. | Zendy; Kavala Veerababurao | Zendy; Guan QiaoZhi | Zendy; Kuo ChunWei | Zendy; Kataria Sunil | Zendy; Shishodia Shifali | Zendy; Janreddy Donala | Zendy; Habib Pateliya Mujjamil | Zendy; Yao ChingFa | Zendy

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The Halonium Ion‐Mediated CC Bond Cleavage of Cyclohexene‐Fused Isoxazoline N ‐Oxides

Author(s) -

Raihan Mustafa J.,

Kavala Veerababurao,

Guan QiaoZhi,

Kuo ChunWei,

Kataria Sunil,

Shishodia Shifali,

Janreddy Donala,

Habib Pateliya Mujjamil,

Yao ChingFa

Publication year - 2012

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201200217

Subject(s) - chemistry , cyclohexene , nitrile , cleavage (geology) , bond cleavage , medicinal chemistry , ring (chemistry) , oxidative cleavage , ion , oxide , photochemistry , stereochemistry , organic chemistry , catalysis , geotechnical engineering , fracture (geology) , engineering

A protocol for the N ‐bromosuccinimide (NBS)‐ and trichloroisocyanuric acid (TCCA)‐mediated cleavage of the CC bond of isoxazoline N ‐oxides, fused with a cyclohexene ring, leading to the production of a long‐chain diketo‐halo‐nitrile skeleton is described. The conversion occurs via the formation of a nitric oxide intermediate.

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