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Sodium Sulfinate‐Mediated trans ‐Stilbene Formation from Benzylic Halides
Author(s) -
Zhao Feng,
Luo Jiaying,
Tan Qi,
Liao Yunfeng,
Peng Shengming,
Deng GuoJun
Publication year - 2012
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201200167
Subject(s) - chemistry , halide , sodium , cis–trans isomerism , transformation (genetics) , medicinal chemistry , combinatorial chemistry , stereochemistry , organic chemistry , biochemistry , gene
A convenient and efficient method for the synthesis of various symmetrical and non‐symmetrical trans ‐stilbene derivatives from benzylic halides in the absence of any transition metals is described. Sodium sulfinates played an important role in this transformation. Various functional groups were well tolerated under the optimized reaction conditions.