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Gold(I)‐Catalyzed Intermolecular [2+2] Cycloadditions between Allenamides and Alkenes
Author(s) -
Faustino Hélio,
Bernal Paloma,
Castedo Luis,
López Fernando,
Mascareñas José L.
Publication year - 2012
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201200047
Subject(s) - chemistry , intermolecular force , cyclobutane , catalysis , combinatorial chemistry , organic chemistry , molecule , ring (chemistry)
3‐(Propa‐1,2‐dien‐1‐yl)oxazolidin‐2‐one works as an efficient two‐carbon partner in a variety of intermolecular gold‐catalyzed [2+2] cycloadditions to alkenes. The transformation represents a simple and practical entry to highly substituted cyclobutane derivatives and takes place with complete regio‐ and stereocontrol.
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