Premium
Palladium Nanoparticles on Thermoresponsive Hydrogels and their Application as Recyclable Suzuki–Miyaura Coupling Reaction Catalysts in Water
Author(s) -
Hong Myeng Chan,
Choi Myung Chan,
Chang Young Wook,
Lee Yongwoo,
Kim Jongsik,
Rhee Hakjune
Publication year - 2012
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201100965
Subject(s) - self healing hydrogels , chemistry , catalysis , palladium , leaching (pedology) , monomer , coupling reaction , nanoparticle , polymer chemistry , suzuki reaction , chemical engineering , organic chemistry , polymer , environmental science , soil science , engineering , soil water
Palladium nanoparticles were immobilized on PNIPAM:4‐VP hydrogels. The resultant püalladium catalysts showed high activities for Suzuki–Miyaura coupling reactions in water. The recyclability of the catalysts was improved by using 4‐VP as a co‐monomer in the hydrogels due to reduced Pd leaching during the reactions.