Pinacol as a New Green Reducing Agent: Molybdenum‐ Catalyzed Chemoselective Reduction of Sulfoxides and Nitroaromatics | Zendy

García Nuria | Zendy; GarcíaGarcía Patricia | Zendy; FernándezRodríguez Manuel A. | Zendy; Rubio Rubén | Zendy; Pedrosa María R. | Zendy; Arnáiz Francisco J. | Zendy; Sanz Roberto | Zendy

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Pinacol as a New Green Reducing Agent: Molybdenum‐ Catalyzed Chemoselective Reduction of Sulfoxides and Nitroaromatics

Author(s) -

García Nuria,

GarcíaGarcía Patricia,

FernándezRodríguez Manuel A.,

Rubio Rubén,

Pedrosa María R.,

Arnáiz Francisco J.,

Sanz Roberto

Publication year - 2012

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201100877

Subject(s) - chemistry , catalysis , reducing agent , pinacol , acetone , chemoselectivity , combinatorial chemistry , organic chemistry , molybdenum

Pinacol is disclosed as a new chemoselective and environmentally benign reducing agent for sulfoxides and nitroaromatics assisted by readily available dichlorodioxomolybdenum(VI) complexes as catalysts. A wide range of substrates including those bearing challenging functional groups has been efficiently and selectively reduced with acetone and water being the only by‐products of these reactions.

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