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Platinum on Carbon‐Catalyzed Precise Reduction Control of Trichloromethyl to Geminal ‐Dichloromethyl Groups
Author(s) -
Imanishi Takahiro,
Fujiwara Yuta,
Sawama Yoshinari,
Monguchi Yasunari,
Sajiki Hironao
Publication year - 2012
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201100778
Subject(s) - geminal , chemistry , catalysis , platinum , hydrogen , dimethylacetamide , organic chemistry , dehydrogenation , solvent , carbon fibers , combinatorial chemistry , composite material , materials science , composite number
Geminal ‐dichloromethyl derivatives could be efficiently synthesized by the highly chemoselective platinum on carbon‐catalyzed mono‐dechlorination of trichloromethyl substrates in dimethylacetamide (DMA) as a specific solvent at 25 °C under a hydrogen atmosphere.