Enantioselective Conjugate Addition of Nitroalkanes to Alkylidenemalonates Promoted by Thiourea‐Based Bifunctional Organocatalysts | Zendy

Chiarucci Michel | Zendy; Lombardo Marco | Zendy; Trombini Claudio | Zendy; Quintavalla Arianna | Zendy

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Enantioselective Conjugate Addition of Nitroalkanes to Alkylidenemalonates Promoted by Thiourea‐Based Bifunctional Organocatalysts

Author(s) -

Chiarucci Michel,

Lombardo Marco,

Trombini Claudio,

Quintavalla Arianna

Publication year - 2012

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201100732

Subject(s) - enantioselective synthesis , bifunctional , chemistry , conjugate , thiourea , cinchona , organocatalysis , organic chemistry , combinatorial chemistry , optically active , cinchona alkaloids , catalysis , mathematical analysis , mathematics

Cinchona alkaloids‐derived bifunctional thioureas efficiently catalyse the enantioselective conjugate addition of nitroalkanes to alkylidenemalonates with syn ‐diastereopreference, opening a route to the synthesis of optically active γ‐amino acid derivatives.

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