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Synthesis of Olefin‐Oxazoline Ligands (OlefOx) by Rhodium(III)‐Catalyzed Oxidative Olefination
Author(s) -
Schröder Nils,
Besset Tatiana,
Glorius Frank
Publication year - 2012
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201100711
Subject(s) - chemistry , rhodium , oxazoline , olefin fiber , catalysis , oxidative phosphorylation , organic chemistry , combinatorial chemistry , biochemistry
The rhodium(III)‐catalyzed oxidative olefination of 2‐aryloxazolines is described and has been employed for the synthesis of olefin‐oxazoline ligands (OlefOx). The highly modular synthesis starting from readily available 2‐aryloxazolines can be performed under an atmosphere of air as the terminal oxidant with catalytic amounts of copper(II)‐acetate.