Tandem Platinum Dichloride Catalysis and Thermal Reaction of Enynes: Versatile Synthetic Platform Based on Bicyclo[4.1.0]hept‐2‐enes | Zendy

Kim Sun Young | Zendy; Park Yujung | Zendy; Son Sori | Zendy; Chung Young Keun | Zendy

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Tandem Platinum Dichloride Catalysis and Thermal Reaction of Enynes: Versatile Synthetic Platform Based on Bicyclo[4.1.0]hept‐2‐enes

Author(s) -

Kim Sun Young,

Park Yujung,

Son Sori,

Chung Young Keun

Publication year - 2012

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201100694

Subject(s) - cycloisomerization , chemistry , platinum , tandem , catalysis , bicyclic molecule , substituent , medicinal chemistry , methylene , aryl , cope rearrangement , stereochemistry , organic chemistry , materials science , alkyl , composite material

A tandem platinum dichloride‐catalyzed cycloisomerization and rearrangement reaction of enynes leads to the formation of 2,4‐pentadienals, 1‐aryl‐tetrahydro‐1 H ‐indenes, or 3‐methylene‐4‐vinylcyclohex‐1‐enes; depending upon the substituent(s) and tether group of the enynes, the platinum dichloride‐catalyzed cycloisomerization products, bicyclo[4.1.0]hept‐2‐enes, undergo a Claisen rearrangement, a 1,5‐hydrogen shift, or a vinylcyclopropane rearrangement.

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