Enantioselective Reaction of Imines and Benzyl Nitriles Using Palladium Pincer Complexes with  C  2 ‐Symmetric Chiral Bis(imidazoline)s | Zendy

Hyodo Kengo | Zendy; Nakamura Shuichi | Zendy; Tsuji Kotaro | Zendy; Ogawa Takahiro | Zendy; Funahashi Yasuhiro | Zendy; Shibata Norio | Zendy

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Enantioselective Reaction of Imines and Benzyl Nitriles Using Palladium Pincer Complexes with C 2 ‐Symmetric Chiral Bis(imidazoline)s

Author(s) -

Hyodo Kengo,

Nakamura Shuichi,

Tsuji Kotaro,

Ogawa Takahiro,

Funahashi Yasuhiro,

Shibata Norio

Publication year - 2011

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201100626

Subject(s) - chemistry , enantioselective synthesis , palladium , pincer movement , imidazoline receptor , yield (engineering) , catalysis , benzene , medicinal chemistry , nitrile , organic chemistry , combinatorial chemistry , medicine , materials science , metallurgy

Enantioselective reactions of a wide variety of benzyl nitriles with N ‐tosylimines catalyzed by novel chiral 1,3‐bis(imidazolin‐2‐yl)benzene‐palladium(II) [Phebim‐Pd(II)] complexes have afforded the respective products in high yield with good enantioselectivity. A reaction mechanism is proposed based on X‐ray crystal structures of palladium complexes.

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