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Aryl Diazonium versus Iodonium Salts: Preparation, Applications and Mechanisms for the Suzuki–Miyaura Cross‐Coupling Reaction
Author(s) -
Bonin Hélène,
Fouquet Eric,
Felpin FrançoisXavier
Publication year - 2011
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201100531
Subject(s) - electrophile , chemistry , aryl , catalysis , coupling reaction , combinatorial chemistry , organic chemistry , alkyl
This review gives an overview of the use of unusual diazonium and iodonium salts as electrophiles for the Suzuki–Miyaura reaction. The discussion mainly focuses, with a critical view, on catalytic systems developed with these electrophiles. The review also discusses their general properties and preparation as well as mechanistic aspects. A last and brief comparison of diazonium versus iodonium salts, by highlighting advantages and drawbacks of both, gives the reader an understandable resumé.