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Ethene‐Induced Temporary Inhibition of Grubbs Metathesis Catalysts
Author(s) -
Scholz Judith,
Loekman Soebiakto,
Szesni Normen,
Hieringer Wolfgang,
Görling Andreas,
Haumann Marco,
Wasserscheid Peter
Publication year - 2011
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201100509
Subject(s) - ruthenium , chemistry , catalysis , metathesis , selectivity , salt metathesis reaction , ionic liquid , combinatorial chemistry , grubbs' catalyst , phase (matter) , catalytic cycle , organic chemistry , polymerization , polymer
Abstract Grubbs‐type catalysts were immobilized in form of supported ionic liquid phase (SILP) materials and applied in the gas‐phase cross‐metathesis of various substrates in order to study the effect of ethene on catalyst activity and stability in detail. From our theoretical and experimental findings we suggest that ethene causes temporary inhibition effects due to a reversible shift of ruthenium complexes from the productive catalytic cycle towards unproductive, dormant ruthenium species. By avoiding the presence of ethene, constant catalytic activity and selectivity for more than 20 days of continuous operation could be realized.