Synthesis of Group 9 Metal‐Olefin Complexes with Identical Ligand Frameworks and Comparison of their Catalytic Activity in [2+2+2] Cycloaddition and other Addition Reactions | Zendy

Weding Nico | Zendy; Jackstell Ralf | Zendy; Jiao Haijun | Zendy; Spannenberg Anke | Zendy; Hapke Marko | Zendy

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Synthesis of Group 9 Metal‐Olefin Complexes with Identical Ligand Frameworks and Comparison of their Catalytic Activity in [2+2+2] Cycloaddition and other Addition Reactions

Author(s) -

Weding Nico,

Jackstell Ralf,

Jiao Haijun,

Spannenberg Anke,

Hapke Marko

Publication year - 2011

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201100489

Subject(s) - chemistry , hydroformylation , cycloaddition , rhodium , cyclopentadienyl complex , hydroboration , olefin fiber , catalysis , ligand (biochemistry) , reactivity (psychology) , cobalt , iridium , medicinal chemistry , organic chemistry , medicine , biochemistry , receptor , alternative medicine , pathology

The preparation and catalytic evaluation of the three group 9 (cyclopentadienyl)metal(trimethylvinylsilane) complexes of the type C 5 H 5 M(H 2 CCHSiMe 3 ) 2 (M=cobalt, rhodium and iridium) are reported. The complexes were investigated in [2+2+2] cycloaddition as well as in hydrogenation, hydroformylation and hydroboration reactions. Despite the identical organic frameworks and structural parameters, the complexes display remarkable reactivity and stability differences.

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