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Highly Efficient and Chemoselective Ruthenium‐Catalyzed Hydrosilylation of Aldehydes
Author(s) -
Do Youngshil,
Han Junghoon,
Rhee Young Ho,
Park Jaiwook
Publication year - 2011
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201100426
Subject(s) - hydrosilylation , ruthenium , chemistry , catalysis , fluorescent light , organic chemistry , chemoselectivity , photochemistry , fluorescence , physics , quantum mechanics
The highly chemoselective hydrosilylation of aldehydes was achieved using a ruthenium catalyst activated by a household fluorescent light (30 W) at or below room temperature. The hydrosilylation was almost exclusive to aldehydes over ketones and olefins.