Stereoselective Epoxidation of Alkenes with Hydrogen Peroxide using a Bipyrrolidine‐Based Family of Manganese Complexes | Zendy

GarciaBosch Isaac | Zendy; Gómez Laura | Zendy; Polo Alfonso | Zendy; Ribas Xavi | Zendy; Costas Miquel | Zendy

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Stereoselective Epoxidation of Alkenes with Hydrogen Peroxide using a Bipyrrolidine‐Based Family of Manganese Complexes

Author(s) -

GarciaBosch Isaac,

Gómez Laura,

Polo Alfonso,

Ribas Xavi,

Costas Miquel

Publication year - 2012

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201100409

Subject(s) - hydrogen peroxide , chemistry , stereoselectivity , manganese , catalysis , peroxide , organic chemistry , hydrogen , medicinal chemistry , combinatorial chemistry , polymer chemistry

Novel manganese complexes containing N 4 ‐tetradentate ligands derived from chiral bipyrrolidinediamines catalyze the stereoselective epoxidation of a wide array of alkenes using low catalyst loadings (0.1 mol%) and hydrogen peroxide (1.2 equiv.) as terminal oxidant. This family of catalysts affords good to excellent yields (80–100%) and moderate to good ee s (40–73%) in short reaction times (30 min) making efficient use of hydrogen peroxide.

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