Premium
CC Bond Formation via CH Activation and CN Bond Formation via Oxidative Amination Catalyzed by Palladium‐ Polyoxometalate Nanomaterials Using Dioxygen as the Terminal Oxidant
Author(s) -
Chng Leng Leng,
Zhang Jie,
Yang Jinhua,
Amoura Makhlouf,
Ying Jackie Y.
Publication year - 2011
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201100362
Subject(s) - chemistry , polyoxometalate , catalysis , amination , palladium , reagent , carbon fibers , oxidative coupling of methane , hydrogen bond , inorganic chemistry , photochemistry , medicinal chemistry , organic chemistry , molecule , composite number , materials science , composite material
An efficient heterogeneous palladium‐polyoxometalate catalyst with the formula Pd‐H 6 PV 3 Mo 9 O 40 /C has been successfully developed for carbon‐carbon (CC) bond formation via carbon‐hydrogen (CH) activation and carbon‐nitrogen (CN) bond formation via oxidative amination using oxygen as the terminal oxidant. The coupling processes are simple, and use relatively mild conditions to form the desired products. In addition, less waste is generated as no additional reagents such as organic/inorganic oxidants are required, and water is the only by‐product generated.